Self-assembled spheres, flowers, and fibers from the same backbone and similar side chains
| Title | Self-assembled spheres, flowers, and fibers from the same backbone and similar side chains |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Singh, AKumar, Krishnamoorthy, K |
| Journal | Langmuir |
| Volume | 33 |
| Issue | 46 |
| Pagination | 13401-13406 |
| Date Published | NOV |
| Type of Article | Article |
| Abstract | Rylene imides (Ms) self-assemble into various nanostructures. Often, the synthesis of unsymmetrical RIs (URIs) is required to achieve nanostructures. However, the synthesis of URIs is nontrivial. Thus, a structurally similar alternative is desirable. iso-Indigo (i-indigo) has a pi core and lactam rings that are structurally similar to the RIs. Unsymmetrical iso-indigo (i-indigo) can be easily synthesized by condensing oxindole and isatin. We have synthesized a series of unsymmetrical i-indigo molecules. In these molecules, the pi-pi interaction, hydrogen bonding, and van der Waals interactions are in operation. Because of these, the molecules self-assemble into spheres, fibers, and dahlia flower morphologies. If the hydrogen bonding interaction is disrupted, then all of them form fibers. Control experiments indicate that the complete absence of hydrogen bonding is deleterious to self-assembly. We also show that the lower analogs of i-indigo are not sufficient to form self-assembled nanostructures. |
| DOI | 10.1021/acs.langmuir.7b02728 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.833 |
Divison category:
Polymer Science & Engineering
Add new comment