Selective synthesis of cumene by isopropylation of benzene using catalytic membrane reactor

TitleSelective synthesis of cumene by isopropylation of benzene using catalytic membrane reactor
Publication TypeJournal Article
Year of Publication2009
AuthorsBokade, VV, Kharul, UK
JournalChemical Engineering Journal
Volume147
Issue2-3
Pagination97-101
Date PublishedAPR
ISSN1385-8947
KeywordsBenzene, Catalytic membrane reactor, cumene, Diisopropyl benzene, Friedel-Craft alkylation
Abstract

Selective isopropylation of benzene to cumene is demonstrated using catalytic membrane reactor (CMR), to our knowledge for the first time and the performance was evaluated against conventional plug flow reactor (PFR). Almost complete elimination of byproducts like polyalkylated benzene and higher aromatics could be made possible by using CMR. These are present in significant amount when reaction is carried out with PFR. The cumene selectivity increased up to a maximum of 97.25% by CMR as against 90.05% with conventional PFR. The effect of reaction parameters that can greatly influence the process economics, such as liquid hourly space velocity (LHSV), reactant mole ratio and catalyst/reactor volume ratio were investigated. Changes in these parameters made for CMR are industrially advantageous. The process by CMR is more economical and ecofriendly than PFR as far as milder process parameters (higher LHSV, lower reactant feed mole ratio, less catalyst require, etc.) and process intensification (reaction and separation in single reactor) are concerned. The study provides new insights for benzene isopropylation reaction. (C) 2008 Elsevier B.V. All rights reserved.

DOI10.1016/j.cej.2008.06.035
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.074
Divison category: 
Catalysis and Inorganic Chemistry
Chemical Engineering & Process Development