Selective aerobic oxidation of alcohols over Au-Pd/sodium titanate nanotubes
Title | Selective aerobic oxidation of alcohols over Au-Pd/sodium titanate nanotubes |
Publication Type | Journal Article |
Year of Publication | 2015 |
Authors | Nepak, D, Darbha, S |
Journal | Catalysis Communications |
Volume | 58 |
Pagination | 149-153 |
Date Published | JAN |
Type of Article | Article |
ISSN | 1566-7367 |
Keywords | aerobic oxidation, Alcohol, Bimetallic Au-Pd catalyst, Sodium titanate nanotubes, TiO2 |
Abstract | catalytic application of Au-Pd nanoparticles supported on sodium titanate nanotubes (NaTNTs) for liquid-phase aerobic oxidation of alcohols is reported, for the first time. This reaction occurs at 80-120 degrees C, 1 atm and solvent-/alkali-free conditions yielding the corresponding carbonyls in high selectivity. This catalyst was reusable and found to be more active/selective than the corresponding monometallic Au and Pd catalysts and Au-Pd/TiO2. Higher dispersion, smaller particle size and higher amount of electron density at gold are the causes for the superior activity of Au-Pd/NaTNT catalyst. (C) 2014 Elsevier B.V. All rights reserved. |
DOI | 10.1016/j.catcom.2014.09.018 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 3.389 |
Divison category:
Catalysis and Inorganic Chemistry
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