[Ru(salen)(NO)] complex encapsulated in mesoporous SBA-16 as catalyst for hydrogenation of ketones
| Title | [Ru(salen)(NO)] complex encapsulated in mesoporous SBA-16 as catalyst for hydrogenation of ketones |
| Publication Type | Journal Article |
| Year of Publication | 2008 |
| Authors | Bordoloi, A, Amrute, AP, Halligudi, SB |
| Journal | Catalysis Communications |
| Volume | 10 |
| Issue | 1 |
| Pagination | 45-48 |
| Date Published | OCT |
| Type of Article | Article |
| ISSN | 1566-7367 |
| Keywords | Encapsulation, Hydrogenation, Ketones, SBA-16, [Ru(salen)(NO)] complex |
| Abstract | SBA-16 mesoporous silica with cubic lm3m structure was synthesized using Pluronic F127 poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer (EO106PO70EO106) and it blends with Pluronic P123 triblock copolymer (EO20PO70EO20) as supramolecular templates. The resulting material was used for encapsulating [Ru(salen)(NO)] complex and used in the hydrogenation of ketones to the corresponding alcohols. The pore entrance size of SBA-16 was precisely tailored by silylation with diphenyldichlorosilane to trap [Ru(salen)(NO)] complex in the cage of SBA-16. Small angle XRD, N-2 sorption measurements, UV-Vis and FT-IR analysis evidences the structural integrity of mesoporous silica as well as the complex. (C) 2008 Elsevier B.V. All rights reserved. |
| DOI | 10.1016/j.catcom.2008.07.029 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.389 |