Ru, Pd doped WO3 nanomaterials: a synergistic effect of noble metals to enhance the acetone response properties

TitleRu, Pd doped WO3 nanomaterials: a synergistic effect of noble metals to enhance the acetone response properties
Publication TypeJournal Article
Year of Publication2022
AuthorsKodam, PM, Ghadage, PA, Nadargi, DY, Shinde, KP, Mulla, IS, Park, JS, Suryavanshi, SS
JournalCeramics International
Volume48
Issue12
Pagination17923-17933
Date PublishedJUN
Type of ArticleArticle
ISSN0272-8842
KeywordsAcetone vapours, Precipitation route, Ru -Pd doping, synergistic effect, WO3
Abstract

Noble metals (NMs) have an enormous impact on the intrinsic properties of the metal oxides. We report the synergistic effect of Ruthenium (Ru) and Palladium (Pd) noble metals on the enhancement of gas sensing properties of pure tungsten oxide (WO3). The gas sensing material is synthesized by simple and straight forward precipitation route, and its physico-chemical analyses are determined using XRD, FESEM, TEM/HRTEM, FFT, UV-Vis, XPS, EDAX, and BET measurements. Use of the developed material as a gas sensor is evaluated using several target gases (oxidizing as well as reducing), with acetone showing the best selectivity. The noble metal doping and hence catalytic action improved the gas response qualities. The synergistic effect of Ru and Pd on WO3 gas response properties are identified, where the effect is 99.80% sensitivity, and lower response/recovery time (10 s and 2 min) at 300 degrees C operating temperature. Nonetheless, the sensors displayed better gas sensing properties even at lower operating temperatures ranging from 200 to 275 degrees C. In addition, the synergistic effect has displayed the dramatic enhancement in the sensitivity to 76.44% at barely 10 ppm acetone concentration. This particular result will undoubtedly be helpful for diagnostic purpose of diabetic patients, and a strong candidate for prospective gas sensing applications, particularly acetone.

DOI10.1016/j.ceramint.2022.03.065
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

5.532

Divison category: 
Physical and Materials Chemistry
Database: 
Web of Science (WoS)

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