Ru-catalyzed redox-neutral cleavage of the N-O bond in isoxazolidines: isatogens to pseudoindoxyls via a one-pot [3+2]-cycloaddition/N-O cleavage
| Title | Ru-catalyzed redox-neutral cleavage of the N-O bond in isoxazolidines: isatogens to pseudoindoxyls via a one-pot [3+2]-cycloaddition/N-O cleavage |
| Publication Type | Journal Article |
| Year of Publication | 2015 |
| Authors | Kumar, CVSuneel, Ramana, CV |
| Journal | Organic Letters |
| Volume | 17 |
| Issue | 12 |
| Pagination | 2870-2873 |
| Date Published | JUN |
| ISSN | 1523-7060 |
| Abstract | A novel metal-catalyzed oxygen atom transfer reaction onto olefins is reported. By taking isatogens as substrates, a one-pot [3 + 2]-cycloaddition of nitrone with olefins followed by the Ru-catalyzed redox-neutral N-O bond cleavage of intermediate isoxazolidine has been executed as a simple method for the synthesis of 2,2-disubstituted pseudoindoxyls. |
| DOI | 10.1021/acs.orglett.5b00837 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.732 |
Divison category:
Organic Chemistry