Regiospecific azidoiodination of alkenes with sodium periodate, potassium iodide, and sodium azide: a high-yield synthesis of beta-iodoazides

TitleRegiospecific azidoiodination of alkenes with sodium periodate, potassium iodide, and sodium azide: a high-yield synthesis of beta-iodoazides
Publication TypeJournal Article
Year of Publication2010
AuthorsChouthaiwale, PV, Karabal, PU, Suryavanshi, G, Sudalai, A
JournalSynthesis-Stuttgart
Issue22
Pagination3879-3882
Date PublishedNOV
ISSN0039-7881
Keywordsalkenes, azides, azidoiodination, beta-iodoazides, regio-specific
Abstract

The combination of sodium periodate, potassium iodide, and sodium azide has been found to be an efficient, simple, and inexpensive reagent system for azidoiodination of alkenes. The regiospecific 1,2-azidoiodination proceeds in an anti-Markovnikov fashion to produce beta-iodoazides in excellent yields.

DOI10.1055/s-0030-1258250
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.260
Divison category: 
Chemical Engineering & Process Development