Reactions of 2,3-dibromonaphthalene-1,4-dione and pyridyl amines: X-ray structures, DFT investigations, and selective detection of the Hg2+ and Ni2+ ions
| Title | Reactions of 2,3-dibromonaphthalene-1,4-dione and pyridyl amines: X-ray structures, DFT investigations, and selective detection of the Hg2+ and Ni2+ ions |
| Publication Type | Journal Article |
| Year of Publication | 2021 |
| Authors | Aggrwal, G, Salunke-Gawali, S, Gejji, SP, Nikalje, M, Chakravarty, D, Verma, PL, Gosavi-Mirkute, P, Harihar, S, Jadhav, M, Puranik, VG |
| Journal | Engineered Science |
| Volume | 14 |
| Pagination | 78-93 |
| Date Published | FEB |
| Type of Article | Article |
| ISSN | 2576-9898 |
| Abstract | In this work, the products formed by the reaction between 2,3-dibromonaphthalene-1,4-dione with (pyridine-2-yl)methanamine and (pyridine-4-yl)methanamine are discussed in detial. The products 2-amino-3-bromonaphthalene-1,4-dione (A) and 2-aminonaphthalene-1,4-dione (B(1)) obtained are characterized through 1H and 13C-NMR, FTIR, mass spectrometry, single-crystal X-ray diffraction experiments, which are in conjunction with wB97X based density functional theory. compound A can effectively and selectively detect Hg2+ and Ni2+ ions, and proposes a potential mechanism of action. |
| DOI | 10.30919/es8d427 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 5.332 |
Divison category:
Physical and Materials Chemistry
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