Reaction of huisgen zwitterion with diaryl-1,2-diones and ketones: an efficient protocol for carbon-nitrogen bond formation
| Title | Reaction of huisgen zwitterion with diaryl-1,2-diones and ketones: an efficient protocol for carbon-nitrogen bond formation |
| Publication Type | Journal Article |
| Year of Publication | 2007 |
| Authors | Nair, V, Biju, AT, Mathew, SC |
| Journal | Synthesis-Stuttgart |
| Issue | 5 |
| Pagination | 697-704 |
| Date Published | JAN |
| Type of Article | Article |
| Keywords | betaines - diazo compounds - hydrazones - ketones - rearrangements |
| Abstract | The reaction of Huisgen zwitterion, derived from triphenylphosphine and dialkyl azodicarboxylate, with diaryl-1,2-diones afforded N,N-dicarboalkoxy monohydrazones via a mechanistically novel rearrangement. Cyclic and acyclic ketones furnished vinyl hydrazinedicarboxylates under similar conditions. |
| DOI | 10.1055/s-2007-965910 |
| Student Name | Council of Scientific & Industrial Research (CSIR) - India |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.652 |
Divison category:
Organic Chemistry