Precursor-dependent heteroatom diversity in luminescent carbon quantum dots: their impact on physicochemical properties and free radical scavenging and antibacterial activities

TitlePrecursor-dependent heteroatom diversity in luminescent carbon quantum dots: their impact on physicochemical properties and free radical scavenging and antibacterial activities
Publication TypeJournal Article
Year of Publication2025
AuthorsKonwar, PMohan, Devi, S, Pandey, SKumar, Devi, KSandhyaran, Devi, ABimolini, Luwang, MNiraj
JournalLangmuir
Volume41
Issue36
Pagination24281-24294
Date PublishedSEP
Type of ArticleArticle
ISSN0743-7463
Abstract

The fabrication of a multifunctional carbon quantum dot (CQD) from a novel carbon source is still continuing to be demanding and fascinating. The carbon precursor plays a crucial role in developing any particular properties of a CQD to suit a specific application. In this study, green (Rhus chinensis fruits) as well as chemical-based (ascorbic acid and urea) carbon sources were used for the fabrication of CQDs using a simple, cost-effective, and eco-friendly method. The various physicochemical and optical properties of R. chinensis fruit-derived CQD (CQD-RCF) and urea-assisted ascorbic acid-derived CQD (CQD-AAU) were thoroughly investigated by using multiple characterization techniques such as XRD, TEM, HR-TEM, Raman, XPS, FT-IR, UV-vis, PL, and zeta potential. The synthesized CQDs were screened for antioxidant properties by a DPPH assay and antibacterial activity by the agar tip-well method. Both of these synthesized CQDs exhibited a variety of dissimilarities regarding their heteroatom compositions and surface functional groups, which subsequently led to an enhanced DPPH radical scavenging efficacy of CQD-AAU and a declared antibacterial efficacy of CQD-RCF. Therefore, the outcome of this study shows that the physicochemical properties and functionalities of CQDs are influenced by the chemical composition of the precursor material.

DOI10.1021/acs.langmuir.5c02171
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

3.7

Divison category: 
Chemical Engineering & Process Development
Database: 
Web of Science (WoS)

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