Practical and general diels-alder reaction of pentafulvenes with arynes
Title | Practical and general diels-alder reaction of pentafulvenes with arynes |
Publication Type | Journal Article |
Year of Publication | 2012 |
Authors | Bhojgude, SSuresh, Kaicharla, T, Bhunia, A, Biju, AT |
Journal | Organic Letters |
Volume | 14 |
Issue | 16 |
Pagination | 4098–4101 |
Date Published | AUG |
Abstract | A high-yielding, versatile and practical Diels–Alder reaction of pentafulvenes with arynes under mild reaction conditions is reported. The aryne generated by the fluoride induced 1,2-elimination of 2-(trimethylsilyl)aryl triflates undergoes efficient cycloaddition with 6-substituted and 6,6-disubstituted pentafulvenes leading to the formation of benzonorbornadiene derivatives. |
DOI | 10.1021/ol301742k |
Funding Agency | Council of Scientific & Industrial Research (CSIR) - India |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 6.142 |
Divison category:
Organic Chemistry