Practical and general diels-alder reaction of pentafulvenes with arynes

TitlePractical and general diels-alder reaction of pentafulvenes with arynes
Publication TypeJournal Article
Year of Publication2012
AuthorsBhojgude, SSuresh, Kaicharla, T, Bhunia, A, Biju, AT
JournalOrganic Letters
Volume14
Issue16
Pagination4098–4101
Date PublishedAUG
Abstract

A high-yielding, versatile and practical Diels–Alder reaction of pentafulvenes with arynes under mild reaction conditions is reported. The aryne generated by the fluoride induced 1,2-elimination of 2-(trimethylsilyl)aryl triflates undergoes efficient cycloaddition with 6-substituted and 6,6-disubstituted pentafulvenes leading to the formation of benzonorbornadiene derivatives.

DOI10.1021/ol301742k
Funding Agency

Council of Scientific & Industrial Research (CSIR) - India

Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)6.142
Divison category: 
Organic Chemistry