Photo-stabilization of EPDM-clay nanocomposites: effect of antioxidant on the preparation and durability

TitlePhoto-stabilization of EPDM-clay nanocomposites: effect of antioxidant on the preparation and durability
Publication TypeJournal Article
Year of Publication2007
AuthorsLonkar, SP, A. Kumar, P, Singh, RPal
JournalPolymers for Advanced Technologies
Volume18
Issue11
Pagination891-900
Date PublishedNOV
Type of ArticleArticle
ISSN1042-7147
Keywordsethylene-propylene-diene monomer, nanocomposites photo-degradation antioxidant and stabilization
Abstract

The present study is to examine the photo-stabilization effect of an antioxidant on the photo-oxidation of ethylene-propylene-diene monomer (EPDM)-clay nanocomposites. During the preparation of EPDM-clay nanocomposites via melt processing antioxidants are usually incorporated along with clay, which allows phenolic antioxidant molecules to get adsorbed onto acidic clay platelets and their interaction with metallic impurities reduces the stabilizing efficiency of the antioxidant. The nanocomposites were obtained by solution dispersion followed by melt compounding of EPDM and organophilic montmorillonite (OMMT). The samples were characterized by conventional tools such as X-ray diffraction (XRD), Fourier Transform Infra Red (FT-IR) spectroscopy, and thermo-gravimetric analysis (TGA). It was found, upon photo-irradiation (lambda > 290 nm) studies by following the changes in functional groups and surface morphology, that photo-degradation was lowered by the antioxidant and the efficiency of the antioxidant could be improved by initial incorporation of antioxidant in the EPDM matrix. In EPDM-clay nanocomposites, a stabilizing activity of the antioxidant was observed above some threshold concentration of the antioxidant. The relationship between the nanoclay reinforcement and stabilizing efficiency in terms of photo-oxidation and surface morphology for their applicability are discussed. The methodology adopted for this study is also justified through our observation. Copyright (C) 2007 John Wiley & Sons, Ltd.

DOI10.1002/pat.925
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)1.823
Divison category: 
Polymer Science & Engineering