Oxidative rearrangement of stilbenes to 2,2-diaryl-2-hydroxyacetaldehydes
| Title | Oxidative rearrangement of stilbenes to 2,2-diaryl-2-hydroxyacetaldehydes |
| Publication Type | Journal Article |
| Year of Publication | 2020 |
| Authors | Kalshetti, RG, V. Ramana, C |
| Journal | ACS Omega |
| Volume | 5 |
| Issue | 39 |
| Pagination | 25199-25208 |
| Date Published | OCT |
| Type of Article | Article |
| ISSN | 2470-1343 |
| Abstract | A one-pot oxone-mediated/iodine-catalyzed oxidative rearrangement of stilbenes leading to 2,2-diary1-2-hydroxyacetaldehydes is described. Control experiments revealed that a 2,2-diarylacetaldehyde was initially formed that undergoes subsequent alpha-hydroxylation. The resulting alpha-hydroxyaldehydes have been subjected to a one-pot Still Gennari olefination followed by cyclization, leading to S,S-diaryl-y-butenolides. |
| DOI | 10.1021/acsomega.0c03328 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.870 |
Divison category:
Organic Chemistry