One-step method for the synthesis of aryl olefins from aryl aldehydes and aliphatic aldehydes

TitleOne-step method for the synthesis of aryl olefins from aryl aldehydes and aliphatic aldehydes
Publication TypeJournal Article
Year of Publication2013
AuthorsBorate, HB, Gaikwad, SH, Kudale, AS, Chavan, SP, Pharande, SG, Wagh, VD, Sawant, VS
JournalTetrahedron Letters
Volume54
Issue12
Pagination1528-1530
Date PublishedMAR
ISSN0040-4039
KeywordsAliphatic aldehyde, Aromatic aldehyde, Aryl olefin, Dicyanoaniline, Malononitrile
Abstract

A conceptually new one-step reaction affording unexpected aryl olefinic product from aromatic aldehyde, aliphatic aldehyde and malononitrile in the presence of acetic acid-ammonium acetate under mild reaction conditions without using any metal catalyst is reported. This novel reaction was used to prepare a number of substituted aryl olefins including new molecules. (c) 2013 Elsevier Ltd. All rights reserved.

DOI10.1016/j.tetlet.2013.01.008
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.391
Divison category: 
Center for Material Characterization (CMC)
Organic Chemistry