One-pot catalytic conversion of sucrose to 1,2-propanediol over titania supported Ni-Ce metal catalyst under milder reaction conditions
Title | One-pot catalytic conversion of sucrose to 1,2-propanediol over titania supported Ni-Ce metal catalyst under milder reaction conditions |
Publication Type | Journal Article |
Year of Publication | 2024 |
Authors | Sreekantan, S, Sreedharan, S, Kirali, AArunima Ba, Yadav, P, Marimuthu, B |
Journal | Biomass Conversion and Biorefinery |
Volume | 14 |
Issue | 19 |
Pagination | 24703-24714 |
Date Published | OCT |
Type of Article | Article |
ISSN | 2190-6815 |
Keywords | Glycol, Low pressure, Low temperature, Ni-Ce catalyst, Sucrose, titania |
Abstract | The increased energy demand and decreasing fossil resources have driven the research community to look into a sustainable, green process to meet the energy demands. India being one of the top producers of sugarcane derived sucrose, and conversion of surplus sucrose to value chemicals is always an advantage. 5%Ni-15%Ce/TiO2 catalyst is found to produce high yield of 1,2-PDO (similar to 74%) under very mild reaction condition of 180 degrees C, 30 bar H-2 for 3-h reaction time. The characterization of the catalyst by using various physicochemical methods indicates the synergy between Ni-Ce bimetal which enhances the selective production of glycol. The low temperature and pressure requirement and the advantage of being the one-pot process will always attract the future scope of commercialization. |
DOI | 10.1007/s13399-023-04781-x |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 7.3 |
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