Nucleophilic ring-opening of benzoxazinones by dbu: some observations
| Title | Nucleophilic ring-opening of benzoxazinones by dbu: some observations |
| Publication Type | Journal Article |
| Year of Publication | 2014 |
| Authors | Baravkar, SB, Roy, A, Gawade, RL, Puranik, VG, Sanjayan, GJ |
| Journal | Synthetic Communications |
| Volume | 44 |
| Issue | 20 |
| Pagination | 2955-2960 |
| Date Published | AUG |
| ISSN | 0039-7911 |
| Keywords | Benzoxazinones, caprolactam, DBU, HATU |
| Abstract | This communication demonstrates the formation of an unusual nucleophilic ring opening of benzoxazinones by 1,8-diazabicycloundec-7-ene (DBU). This observation contradicts the intrinsic feature of a hindered nonnucleophilic base like DBU. Confirmation of the product was achieved via single-crystal X-ray diffraction studies. |
| DOI | 10.1080/00397911.2014.910529 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 1.065 |
Divison category:
Center for Material Characterization (CMC)
Organic Chemistry