Nitrogen-rich porous covalent imine network (CIN) material as an efficient catalytic support for C-C coupling reactions

TitleNitrogen-rich porous covalent imine network (CIN) material as an efficient catalytic support for C-C coupling reactions
Publication TypeJournal Article
Year of Publication2012
AuthorsBhunia, MK, Das, SK, Pachfule, P, Banerjee, R, Bhaumik, A
JournalDalton Transactions
Volume41
Issue4
Pagination1304-1311
Date PublishedDEC
Type of ArticleArticle
ISSN1477-9226
Abstract

In an effort to expand the realm of possibilities of nitrogen-rich porous materials that could be used in catalysis, herein we report the synthesis of a new highly nitrogen rich (ca. 45%) porous covalent imine network (CIN-1) material employing simple Schiff base chemistry and further grafting its surface with palladium. Pd-loaded CIN-1 support acts as a truly heterogeneous catalyst towards Suzuki C-C coupling reaction between aryl halides with arylboronic acids. High surface area and excellent accessibility of the catalytic sites make it very efficient for heterogeneous catalysis. The stability of the catalyst due to intimate contact between nitrogen-rich organic support and metal allows several reuses with only a minor loss in catalytic activity.

DOI10.1039/c1dt11350j
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.806
Divison category: 
Physical and Materials Chemistry