New synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis
Title | New synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis |
Publication Type | Journal Article |
Year of Publication | 2005 |
Authors | Kotha, S, Mandal, K, Arora, KK, Pedireddi, R |
Journal | Advanced Synthesis & Catalysis |
Volume | 347 |
Issue | 9 |
Pagination | 1215-1218 |
Date Published | JUL |
ISSN | 1615-4150 |
Keywords | Cyclophanes, olefin metathesis, Palladium, ruthenium, Suzuki-Miyaura cross-coupling |
Abstract | The synthesis of a [1.1.6] metapara cyclophane derivative, 1,5(1,4),3(1,3)-tribenzenacycloun-decaphan-8-ene-6,11-dione, has been achieved via the Suzuki-Miyaura cross-coupling of alpha,alpha'-dibromo-m-xylene with an arylboronic acid derivative followed by an allylation and ring-closing metathesis reaction sequence. |
DOI | 10.1002/adsc.200404373 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 6.453 |
Divison category:
Organic Chemistry