Natural kaolinitic clay: a remarkable catalyst for highly regioselective chlorination of arenes with Cl-2 or SO2Cl2
Title | Natural kaolinitic clay: a remarkable catalyst for highly regioselective chlorination of arenes with Cl-2 or SO2Cl2 |
Publication Type | Journal Article |
Year of Publication | 2006 |
Authors | Jayachandran, B, Phukan, P, Daniel, T, Sudalai, A |
Journal | Indian Journal of Chemistry Section B-Organic Chemistry Including Medicinal Chemistry |
Volume | 45 |
Issue | 4 |
Pagination | 972-975 |
Date Published | APR |
Type of Article | Article |
ISSN | 0376-4699 |
Keywords | Aniline, chlorination, chlorine, ortho-chloroaniline, sulfuryl chloride |
Abstract | Natural kaolinitic clay containing transition metals such as Fe and Ti in its lattice has been found to exhibit unusual regioselectivity in the liquid-phase chlorination of arenes with either Cl-2 or SO2Cl2 as the chlorinating agent para-Chlorinated products are predominant for most of the substrates with an exceptional case of ortho-selectivity for the chlorination of aniline. |
Type of Journal (Indian or Foreign) | Indian |
Impact Factor (IF) | 0.471 |
Divison category:
Chemical Engineering & Process Development