Nanowires of metal-organic complex by photocrystallization: a system to achieve addressable electrically bistable devices and memory elements
Title | Nanowires of metal-organic complex by photocrystallization: a system to achieve addressable electrically bistable devices and memory elements |
Publication Type | Journal Article |
Year of Publication | 2008 |
Authors | Rath, AKumar, Dhara, K, Banerjee, P, Pal, AJ |
Journal | Langmuir |
Volume | 24 |
Issue | 11 |
Pagination | 5937–5941 |
Date Published | MAY |
Abstract | A new method has been achieved to form a Cu:benzoquinone derivative (DDQ) charge-transfer complex by the photoexcitation of [Cu(DDQ)2(CH3COO)2] (1) that has been synthesized by the reaction of DDQ and hydrated cupric acetate in acetonitrile. Photoexcitation of coordinated complex 1 leads to the formation of charge-transfer complex Cu2+(DDQ•−)2 (2). The charge transfer complex 2, when spun on solid substrates, forms nanowires. Sandwich structures of 2 exhibit electrical bistability associated with memory phenomenon. Read-only and random-access memory phenomena are evidenced in nanowires of 2 providing a route to attend the issues pertaining to the addressibility of organic memory devices. |
DOI | 10.1021/la703871g |
Funding Agency | Council of Scientific & Industrial Research (CSIR) - India |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 4.268 |