Nanocrystalline Ce doped CoFe2O4 as an acetone gas sensor

TitleNanocrystalline Ce doped CoFe2O4 as an acetone gas sensor
Publication TypeJournal Article
Year of Publication2014
AuthorsKhandekar, MS, Tarwal, NL, Mulla, IS, Suryavanshi, SS
JournalCeramics International
Volume40
Issue1
Pagination447-452
Date PublishedJAN
ISSN0272-8842
KeywordsCoFe2O4, Ferrite, Gas sensor, Molten-salt method, TEM
Abstract

Nanocrystalline CoFe2-xCexO4 ferrites (x=0, 0.04, 0.08) were synthesized by using the inexpensive, simple and eco-friendly molten-salt (M-S) method. Effects of Ce doping on the structural, morphological and gas sensing properties of the CoFe2O4 ferrite were investigated. X-ray diffraction (XRD) analysis revealed the formation of spinel CoFe2O4. Transmission electron microscopy (TEM) investigations showed that the synthesized ferrite is made up of very fine spherical nanoparticles. Furthermore, the gas response of nanocrystalline ferrite materials was investigated in the temperature range of 200-450 degrees C toward the reducing gases like liquefied petroleum gas (LPG), acetone, ethanol and ammonia. The sensor response was found to be sensitive and selective toward acetone as compared to other reducing gases. It is observed that the addition of Ce (4 wt%) strongly influenced the response and the operating temperature of the sensor material and thus can serve as acetone-sensing sensors. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

DOI10.1016/j.ceramint.2013.06.021
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.88
Divison category: 
Physical and Materials Chemistry