MgBr2-mediated ionic Diels-Alder reaction of acetals of alpha,beta-unsaturated aldehydes and ketones with 1,3-dienes

TitleMgBr2-mediated ionic Diels-Alder reaction of acetals of alpha,beta-unsaturated aldehydes and ketones with 1,3-dienes
Publication TypeJournal Article
Year of Publication2007
AuthorsChavan, SP, Ethiraj, KS, Dantale, SW
JournalSynthetic Communications
Volume37
Issue14
Pagination2337-2343
Date PublishedJUL
Type of ArticleArticle
ISSN0039-7911
Keywordsacetals, Catalysts, Diels-Alder reactions, dienes
Abstract

A facile, mild, and efficient methodology for the ionic Diels-Alder reaction of acetals of alpha,beta-unsaturated ketones and aldehydes as dienophiles with various 1,3- dienes employing MgBr2 as the Lewis acid catalyst to furnish corresponding Diels-Alder adducts at ambient temperature is described.

DOI10.1080/00397910701410814
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)1.065
Divison category: 
Organic Chemistry