Methane reforming with carbon dioxide over La-Ni-x-Ce1-x mixed oxide catalysts

TitleMethane reforming with carbon dioxide over La-Ni-x-Ce1-x mixed oxide catalysts
Publication TypeJournal Article
Year of Publication2014
AuthorsSagar, TV, Sreelatha, N, Hanmant, G, Upendar, K, Lingaiah, N, Rao, KSeetha Ram, Satyanarayana, CVV, Reddy, IAK, Prasad, PSSai
JournalIndian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry
Volume53
Issue4-5
Pagination478-483
Date PublishedFEB
ISSN0376-4710
KeywordsCarbon dioxide reforming, Catalysts, Cerium, Dry reforming, Hydrothermal synthesis, Lanthanum, Methane reforming, Mixed oxides, Nickel
Abstract

La-Ni-x-Ce1-x mixed oxide (0 <= x <= 1) catalysts have been hydrothermally prepared, characterized by physico-chemical techniques and evaluated for CO2 reforming of methane. High conversions are achieved for both methane and carbon dioxide over the LaNi0.6Ce0.4O3 catalyst tested under the conditions of CO2/CH4/N-2 ratio of 80/80/80. (total flow rate = 240 mL/min), space velocity of 28,800 h(-1) and at a temperature of 800 degrees C. The H-2/CO ratio in the syngas is stable at 0.93 +/- 0.02. Exchanging Ni with Ce, rather than with La as reported in the literature, appears to be a better option for the improved performance of the catalysts.

Type of Journal (Indian or Foreign)Indian
Impact Factor (IF)0.84
Divison category: 
Catalysis and Inorganic Chemistry