Metal-induced reductive ring opening of 1,2,4,5-tetrazines: Three resulting coordination alternatives, including the new non-innocent 1,2-diiminohydrazido(2-) bridging ligand system

TitleMetal-induced reductive ring opening of 1,2,4,5-tetrazines: Three resulting coordination alternatives, including the new non-innocent 1,2-diiminohydrazido(2-) bridging ligand system
Publication TypeJournal Article
Year of Publication2006
AuthorsMaji, S, Sarkar, B, Patra, S, Fiedler, J, Mobin, SM, Puranik, VG, Kaim, W, Lahiri, GKumar
JournalInorganic Chemistry
Volume45
Issue3
Pagination1316-1325
Date PublishedFEB
Type of ArticleArticle
ISSN0947-6539
Keywordscrystal engineering, hydrogen bonds, molecular, recocynition, Self-assembly, supramolecular chemistry
Abstract

{Reaction of 3,6-diaryl-1,2,4,5-tetrazines (aryl = R = phenyl, 2-furyl or 2-thienyl) with 2 equiv of Ru(acac)(2)(CH3-CN)(2) results in reductive tetrazine ring opening to yield diruthenium complexes [

DOI10.1021/ic051532p
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

4.82

Divison category: 
Center for Material Characterization (CMC)
Physical and Materials Chemistry