Metal-free hypervalent iodine/tempo mediated oxidation of amines and mechanistic insight into the reaction pathways

TitleMetal-free hypervalent iodine/tempo mediated oxidation of amines and mechanistic insight into the reaction pathways
Publication TypeJournal Article
Year of Publication2018
AuthorsBansode, AH, Suryavanshi, G
JournalRSC Advances
Volume8
Issue56
Pagination32055-32062
Date PublishedSEP
Type of ArticleArticle
AbstractA highly efficient metal free approach for the oxidation of primary and secondary amines to their corresponding aldehydes and ketones using PhI(OAc)2 in combination with a catalytic amount of TEMPO as an oxidizing agent is described. This protocol is rapid and provides diverse products under milder reaction conditions in excellent yields. In addition, the mechanistic study is well demonstrated by spectroscopic methods.
DOI10.1039/c8ra07451h
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.936
Divison category: 
Chemical Engineering & Process Development

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