MCM-41-supported platinum carbonyl cluster-derived asymmetric hydrogenation catalyst
| Title | MCM-41-supported platinum carbonyl cluster-derived asymmetric hydrogenation catalyst |
| Publication Type | Journal Article |
| Year of Publication | 2005 |
| Authors | Basu, S, Paul, H, Gopinath, CS, Bhaduri, S, Lahiri, GKumar |
| Journal | Journal of Catalysis |
| Volume | 229 |
| Issue | 2 |
| Pagination | 298-302 |
| Date Published | JAN |
| Type of Article | Article |
| ISSN | 0021-9517 |
| Keywords | asymmetric catalysis, functionalized inorganic oxides, hydrogenation catalysts, platinum carbonyl cluster |
| Abstract | Anionic platinum carbonyl cluster has been ion paired with cinchonidium groups that are chemically bound to the surface of MCM-41 and fumed silica. In the hydrogenation of methyl pyruvate or acetophenone the fumed silica-based catalyst gives zero enantioselectivity, but under optimum conditions enantiomeric excesses of >90 and similar to40%, respectively, are obtained with the MCM-41-based catalyst. (C) 2004 Elsevier Inc. All rights reserved. |
| DOI | 10.1016/j.jcat.2004.11.010 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 7.354 |
Divison category:
Catalysis and Inorganic Chemistry