MCM-41-supported phosphotungstic acid-catalyzed cleavage of C-O bond in allyl aryl ethers
| Title | MCM-41-supported phosphotungstic acid-catalyzed cleavage of C-O bond in allyl aryl ethers |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Sakate, SS, Kamble, SB, Chikate, RC, Rode, CV |
| Journal | New Journal of Chemistry |
| Volume | 41 |
| Issue | 12 |
| Pagination | 4943-4949 |
| Date Published | JUN |
| Type of Article | Article |
| Abstract | Removal of the protecting allyl group from allyl aryl ethers in the presence of other oxygen protecting groups was successfully achieved using a solid acid supported on the high surface area material MCM-41. The catalyst showed excellent activity in the presence of various electron withdrawing, electron donating, and oxidizable functional groups. The methodology is also very useful for the removal of protecting allyl groups of various natural products such as vanillin, isovanillin, and other oxygen functionalized aldehydes and ketones. |
| DOI | 10.1039/c7nj00375g |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.277 |
Divison category:
Organic Chemistry
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