Ligand/additive/base-free C(sp(2))-H activation and isocyanide insertion in PEG-400: synthesis of indolizine/imidazoline-fused heterocycles
| Title | Ligand/additive/base-free C(sp(2))-H activation and isocyanide insertion in PEG-400: synthesis of indolizine/imidazoline-fused heterocycles |
| Publication Type | Journal Article |
| Year of Publication | 2018 |
| Authors | K. Kumar, S, Rajesham, B, N. Kumar, P, Ramulu, MSiddi, Dandela, R |
| Journal | ChemistrySelect |
| Volume | 3 |
| Issue | 17 |
| Pagination | 4581-4585 |
| Date Published | MAY |
| Abstract | A ligand/base/metal oxidant free Pd-catalyzed C(sp(2))-H activation, followed by isocyanide insertion to synthesize indolizine/imidazoline fused heterocyclics in PEG-400 as a recyclable solvent. The present transformation is greener and an efficient strategy using oxygen as external oxidant. The spectroscopic properties of selected indolizine/imidazoline fused heterocyclics were studied by UV-visible and fluorescence spectroscopy. |
| DOI | 10.1002/slct.201800397 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | Not Available |
Divison category:
Organic Chemistry