Large-bite bisphosphite, 1,3-C6H4OPOC10H6(μ-S)C10H6O2: synthesis, copper(I), and gold(I) complexes
| Title | Large-bite bisphosphite, 1,3-C6H4OPOC10H6(μ-S)C10H6O2: synthesis, copper(I), and gold(I) complexes |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Balakrishna, MS, Kumar, P, Punji, B, Mague, JT |
| Journal | Journal of Organometallic Chemistry |
| Volume | 695 |
| Issue | 7 |
| Pagination | 981–986 |
| Date Published | NOV |
| Abstract | Large-bite bisphosphite ligand 1,3-C6H4{OPOC10H6(μ-S)C10H6O}2 (3), is obtained by reacting chlorophosphonite {OC10H6(μ-S)C10H6O}PCl (2) with resorcinol in the presence of triethylamine. Treatment of 3 with CuCl in 1:1 molar ratio produces a 1D-coordination polymer [CuCl{(–OC10H6(μ-S)C10H6O–)P(–OC6H4O–)P(–OC10H6(μ-S)C10H6O–)}-κP,κP]∞ (4) in good yield. Similar reaction of 3 with two equivalents of AuCl(SMe2) affords a dinuclear complex, [Au2Cl2{(–OC10H6(μ-S)C10H6O–)P(–OC6H4O–)P(–OC10H6(μ-S)C10H6O–)}-κP,κP] (5). Single crystal X-ray structures of the ligand 3 and the complexes 4 and 5 are reported. The gold complex 5 shows dimeric structure supported by strong Au···Au aurophilic interactions. |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.205 |
Divison category:
Organic Chemistry