Iodine-mediated oxidative rearrangement of alpha,beta-unsaturated diaryl ketones: a facile access to 1,2-diaryl diketones
| Title | Iodine-mediated oxidative rearrangement of alpha,beta-unsaturated diaryl ketones: a facile access to 1,2-diaryl diketones |
| Publication Type | Journal Article |
| Year of Publication | 2019 |
| Authors | Bansode, AH, Suryavanshi, G |
| Journal | ACS Omega |
| Volume | 4 |
| Issue | 6 |
| Pagination | 9636-9644 |
| Date Published | JUN |
| Type of Article | Article |
| ISSN | 2470-1343 |
| Abstract | A metal-free oxidative rearrangement was explored for the synthesis of 1,2-diaryl diketones by utilizing alpha, beta-unsaturated diaryl ketones and I-2/TBHP in good to high yields. The reaction proceeds via oxidative aryl migration, followed by C-C bond cleavage. A simple and high-yielding protocol was developed for the synthesis of a wide range of 1,2-diaryl diketones, which are the backbone for a variety of medicinally important molecules. |
| DOI | 10.1021/acsomega.9b00833 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.584 |
Divison category:
Chemical Engineering & Process Development