Intrinsic viscosity of aqueous solutions of carboxymethyl guar in the presence and in the absence of salt

TitleIntrinsic viscosity of aqueous solutions of carboxymethyl guar in the presence and in the absence of salt
Publication TypeJournal Article
Year of Publication2008
AuthorsBadiger, MV, Gupta, NR, Eckelt, J, Wolf, BA
JournalMacromolecular Chemistry and Physics
Volume209
Issue20
Pagination2087-2093
Date PublishedOCT
Type of ArticleArticle
ISSN1022-1352
KeywordsBiopolymers, Carboxymethyl guar, intrinsic viscosity, polyelectrolyte, salt-free solutions
Abstract

Intrinsic viscosities were determined for solutions of CMG in pure water and 0.9 wt.-% aqueous NaCl. To avoid the 0/0-type extrapolation typical for Huggins plots, a new procedure was used. For CMG and pure water, this requires only two adjustable parameters: the specific hydrodynamic volume of the polymer in the limit of infinite dilution and a hydrodynamic interaction parameter. The intrinsic viscosity of CMG (no salt) at room temperature is 6 050 mL . g(-1); approximately half as large as that of Na-PSS of comparable molar mass. The ratio of the intrinsic viscosities with and without salt is approximate to 7 for CMG, as compared to >100 for Na-PSS. The reasons 1:5 5 for the different behaviors of the two types of polyelectrolytes are being discussed.

DOI10.1002/macp.200800238
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.495
Divison category: 
Polymer Science & Engineering