Intrinsic viscosity of aqueous solutions of carboxymethyl guar in the presence and in the absence of salt
| Title | Intrinsic viscosity of aqueous solutions of carboxymethyl guar in the presence and in the absence of salt |
| Publication Type | Journal Article |
| Year of Publication | 2008 |
| Authors | Badiger, MV, Gupta, NR, Eckelt, J, Wolf, BA |
| Journal | Macromolecular Chemistry and Physics |
| Volume | 209 |
| Issue | 20 |
| Pagination | 2087-2093 |
| Date Published | OCT |
| Type of Article | Article |
| ISSN | 1022-1352 |
| Keywords | Biopolymers, Carboxymethyl guar, intrinsic viscosity, polyelectrolyte, salt-free solutions |
| Abstract | Intrinsic viscosities were determined for solutions of CMG in pure water and 0.9 wt.-% aqueous NaCl. To avoid the 0/0-type extrapolation typical for Huggins plots, a new procedure was used. For CMG and pure water, this requires only two adjustable parameters: the specific hydrodynamic volume of the polymer in the limit of infinite dilution and a hydrodynamic interaction parameter. The intrinsic viscosity of CMG (no salt) at room temperature is 6 050 mL . g(-1); approximately half as large as that of Na-PSS of comparable molar mass. The ratio of the intrinsic viscosities with and without salt is approximate to 7 for CMG, as compared to >100 for Na-PSS. The reasons 1:5 5 for the different behaviors of the two types of polyelectrolytes are being discussed. |
| DOI | 10.1002/macp.200800238 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.495 |
