Intrinsic viscosity of aqueous solutions of carboxymethyl guar in the presence and in the absence of salt
Title | Intrinsic viscosity of aqueous solutions of carboxymethyl guar in the presence and in the absence of salt |
Publication Type | Journal Article |
Year of Publication | 2008 |
Authors | Badiger, MV, Gupta, NR, Eckelt, J, Wolf, BA |
Journal | Macromolecular Chemistry and Physics |
Volume | 209 |
Issue | 20 |
Pagination | 2087-2093 |
Date Published | OCT |
Type of Article | Article |
ISSN | 1022-1352 |
Keywords | Biopolymers, Carboxymethyl guar, intrinsic viscosity, polyelectrolyte, salt-free solutions |
Abstract | Intrinsic viscosities were determined for solutions of CMG in pure water and 0.9 wt.-% aqueous NaCl. To avoid the 0/0-type extrapolation typical for Huggins plots, a new procedure was used. For CMG and pure water, this requires only two adjustable parameters: the specific hydrodynamic volume of the polymer in the limit of infinite dilution and a hydrodynamic interaction parameter. The intrinsic viscosity of CMG (no salt) at room temperature is 6 050 mL . g(-1); approximately half as large as that of Na-PSS of comparable molar mass. The ratio of the intrinsic viscosities with and without salt is approximate to 7 for CMG, as compared to >100 for Na-PSS. The reasons 1:5 5 for the different behaviors of the two types of polyelectrolytes are being discussed. |
DOI | 10.1002/macp.200800238 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 2.495 |