Intramolecular selective hydrogenation of cinnamaldehyde over CeO2-ZrO2-supported Pt catalysts

TitleIntramolecular selective hydrogenation of cinnamaldehyde over CeO2-ZrO2-supported Pt catalysts
Publication TypeJournal Article
Year of Publication2012
AuthorsBhogeswararao, S, Srinivas, D
JournalJournal of Catalysis
Volume285
Issue1
Pagination31-40
Date PublishedJAN
ISSN0021-9517
Keywordsalpha, beta-Unsaturated aldehyde, Ceria-zirconia, Cinnamaldehyde, Hydrogenation, Promotion by alkali ions, Supported Pt catalyst
Abstract

Selective liquid phase hydrogenation of cinnamaldehyde is reported, for the first time, over CeO2, ZrO2, and CeO2-ZrO2-supported Pt catalysts. Cinnamyl alcohol is the selective product. These catalysts are highly active and selective even at 25 degrees C and found to be superior to most of the hitherto known supported Pt catalysts. Alkali addition (NaOH) has enhanced the performance of these catalysts. At an optimized reaction condition, 95.8% conversion of cinnamaldehyde and 93.4% selectivity of cinnamyl alcohol have been obtained. Acidity of the support (due to the presence of ZrO2 component) and higher electron density at Pt (due to CeO2 component) are attributed to be responsible for the superior catalytic activity of Pt supported on CeO2-ZrO2 composite material. (C) 2011 Elsevier Inc. All rights reserved.

DOI10.1016/j.jcat.2011.09.006
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)5.787
Divison category: 
Catalysis and Inorganic Chemistry