Insertion copolymerization of difunctional polar vinyl monomers with ethylene
Title | Insertion copolymerization of difunctional polar vinyl monomers with ethylene |
Publication Type | Journal Article |
Year of Publication | 2015 |
Authors | Gaikwad, SR, Deshmukh, SS, Gonnade, RG, Rajamohanan, PR, Chikkali, SH |
Journal | ACS Macro Letters |
Volume | 4 |
Issue | 9 |
Pagination | 933-937 |
Date Published | SEP |
ISSN | 2161-1653 |
Abstract | A single-step synthesis, structural characterization and application of a neutral, acetonitrile ligated, palladium-phosphinesulfonate complex [{P<\^>O}PdMe(L)] (P<\^>O = K-2-P,O Ar2PC6H4SO2O with Ar = 2-MeOC6H4; L = CH3CN) (3) in coordination/insertion copolymerization of ethylene with difunctional olefin is investigated. In a significant development, complex 3 was found to catalyze insertion copolymerization of industrially relevant 1,1-disubstituted difunctional vinyl monomers for the first time. Thus, insertion copolymerization of ethyl-2-cyanoacrylate (ECA or super glue) and trifluoromethyl acrylic acid (TFMAA) with ethylene produced the corresponding copolymers with 6.5% ECA and 3% TFMAA incorporation. Increasing the concentration of difunctional olefins led to higher incorporation but at the expense of lower activities. These observations indicate that complex 3 tolerates difunctional vinyl monomers and provides direct access to difunctional polyolefins that have not been attempted before. |
DOI | 10.1021/acsmacrolett.5b00562 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 5.766 |