Influence of Pd-loading on gas sensing characteristics of SnO2 thick films

TitleInfluence of Pd-loading on gas sensing characteristics of SnO2 thick films
Publication TypeJournal Article
Year of Publication2012
AuthorsBagal, LK, Patil, JY, Mulla, IS, Suryavanshi, SS
JournalCeramics International
Volume38
Issue6
Pagination4835-4844
Date PublishedAUG
ISSN0272-8842
KeywordsLPG sensor, Palladium, SnO2, Thick film
Abstract

Nanocrystalline pristine and 0.5, 1.5 and 3.0 wt% Pd loaded SnO2 were synthesized by a facile co-precipitation route. These powders were screen-printed on alumina substrates to form thick films to investigate their gas sensing properties. The crystal structure and morphology of different samples were characterized by using X-ray diffraction, scanning electron microscopy and transmission electron microscopy techniques. The 3.0 wt% Pd:SnO2 showed response of 85% toward 100 ppm of LPG at operating temperature of 250 degrees C with fast response (8 s) and quick recovery time (24 s). The high response toward LPG on Pd loading can be attributed to lowering of crystallite size (9 nm) as well as the role of Pd particles in exhibiting spill-over mechanism on the SnO2 surface. Also selectivity of 3.0 wt% Pd:SnO2 toward LPG was confirmed by measuring its response to other reducing gases like acetone (CH3COCH3), ethanol (C2H5OH) and ammonia (NH3) at optimum operating temperature. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

DOI10.1016/j.ceramint.2012.02.073
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)1.789
Divison category: 
Physical and Materials Chemistry