Hypervalent iodine(iii) induced oxidative olefination of benzylamines using Wittig reagents

TitleHypervalent iodine(iii) induced oxidative olefination of benzylamines using Wittig reagents
Publication TypeJournal Article
Year of Publication2021
AuthorsRamavath, V, Rupanawar, BD, More, SG, Bansode, AH, Suryavanshi, G
JournalNew Journal of Chemistry
Volume45
Issue19
Pagination8806-8813
Date PublishedMAY
Type of ArticleArticle
ISSN1144-0546
Abstract

We have developed hypervalent iodine(iii) induced oxidative olefination of primary and secondary benzylamines using 2C-Wittig reagents, which provides easy access to alpha,beta-unsaturated esters. Mild reaction conditions, good to excellent yields with high (E) selectivity, and a broad substrate scope are the key features of this reaction. We have successfully carried out the gram-scale synthesis of alpha,beta-unsaturated esters.

DOI10.1039/d1nj01170g, Early Access Date = APR 2021
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)3.591
Divison category: 
Chemical Engineering & Process Development

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