Hydrogen bond directed honeycomb-like porous network structure of tris (bipyridyl-glycoluril)cobalt(III) chloride

TitleHydrogen bond directed honeycomb-like porous network structure of tris (bipyridyl-glycoluril)cobalt(III) chloride
Publication TypeJournal Article
Year of Publication2011
AuthorsKawade, VA, Kumbhar, AS, Erxleben, A, Pachfule, P, Banerjee, R
JournalCrystengcomm
Volume13
Issue17
Pagination5289-5291
Date PublishedJUL
ISSN1466-8033
Abstract

The [Co(bpg)3]Cl-3 complex (1), where bpg = 4b, 5, 7, 7a-tetrahydro4b,7a-epiminomethan-oimino-6H-imidazo [4,5-f][1,10]-phenanthroline-6,13-dione has been synthesized and characterized by various spectroscopic techniques and single crystal X-ray diffraction. The combination of bipyridyl-glycoluril (bpg) ligands and cobalt ion self-organise to form a honeycomb-like porous network structure resulting in the formation of zeolite like channels which adsorb gases, is described.

DOI10.1039/c1ce05376k
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.68
Divison category: 
Physical and Materials Chemistry