Hybrid silylene-Pd catalyst: efficient C-N cross-coupling of sterically bulky amines and chiral amines
| Title | Hybrid silylene-Pd catalyst: efficient C-N cross-coupling of sterically bulky amines and chiral amines |
| Publication Type | Journal Article |
| Year of Publication | 2024 |
| Authors | Kaulage, SH, Parvin, N, Khopade, KV, Khan, S |
| Journal | Chemical Communications |
| Volume | 60 |
| Issue | 73 |
| Pagination | 9958-9961 |
| Date Published | SEP |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Abstract | Herein, we report a catalytic system with N-heterocyclic silylene (NHSi)-phosphine-based hybrid bidentate ligands [PhC(NtBu)2SiN(PR2)(2,6-iPr2-C6H3)] and Pd(dba)2, which serves as an effective catalyst for C-N cross-coupling of a wide range of sterically bulky amines and optically active amines, which is challenging otherwise. Herein, we report a hybrid silylene-based bidentate ligand (SiNP)-Pd(0) catalytic system, which performs the C-N coupling of difficult substrates, e.g., sterically bulky amines and chiral amines. |
| DOI | 10.1039/d4cc03108c |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.9 |
Divison category:
Polymer Science & Engineering
Database:
Web of Science (WoS)