Highly selective catalytic hydrogenation of arenes using rhodium nanoparticles supported on multiwalled carbon nanotubes

TitleHighly selective catalytic hydrogenation of arenes using rhodium nanoparticles supported on multiwalled carbon nanotubes
Publication TypeJournal Article
Year of Publication2008
AuthorsKakade, BA, Sahoo, S, Halligudi, SB, Pillai, VK
JournalJournal of Physical Chemistry C
Volume112
Issue35
Pagination13317-13319
Date PublishedSEP
Type of ArticleArticle
ISSN1932-7447
Abstract

Rhodium nanoparticles (RhNPs; 4.9 +/- 0.4 nm) supported on multiwalled carbon nanotubes (Rh/MWNT), prepared by simple microwave treatment, show a remarkable catalytic activity for arene hydrogenation with enhanced turnover numbers of similar to 10000; disubstituted arenes show selective conversion of thermodynamically less favorable cis products (>80%). A series of arenes have been tested using various Rh-based catalysts, and a comparison of the results with that of reported rhodium catalysts shows unique selectivity under mild conditions.

DOI10.1021/jp804843h
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)4.509
Divison category: 
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry