High performance and enhanced stability of Mn-Co3V2O8 coral-like structure for supercapacitor applications

TitleHigh performance and enhanced stability of Mn-Co3V2O8 coral-like structure for supercapacitor applications
Publication TypeJournal Article
Year of Publication2025
AuthorsVenkatesan, S, Rajkumar, P, Radhika, G, Iyer, MS, Manigandan, R, Rajaiah, DKumar, Radhakrishnan, S, Raman, S, Marimuthu, S, Kim, J
JournalACS Applied Energy Materials
Volume8
Issue13
Pagination9419-9429
Date PublishedJUN
Type of ArticleArticle
ISSN2574-0962
KeywordsCo3V2O8, Electrode material, Energy storage, stability, supercapacitor
Abstract

This study explores Mn-doped Co3V2O8 as a promising electrode material for high-performance supercapacitors. Mn doping significantly enhances the electrochemical properties of Co3V2O8, resulting in improved specific capacitance and cycling stability. Structural characterization reveals a coral-like morphology that increases the active sites and facilitates efficient charge transport and ion diffusion. Electrochemical tests show an impressive specific capacitance of 2352 F g(-1) in 2 M KOH at 1 A g(-1). For the assembled MCV5//AC asymmetric supercapacitor device, it has a high capacitance retention of 87.6% and a high Coulombic efficiency of 96% over 5000 cycles. The developed asymmetric MCV5/AC supercapacitor device achieved an energy density of 45 Wh kg(-1) and a power density of 750 W kg(-1). These findings establish Mn-doped Co3V2O8 as a durable and efficient electrode material, offering valuable insights into the relationship between the morphology and electrochemical performance. This work provides a foundation for the development of advanced materials for sustainable energy storage applications

DOI10.1021/acsaem.5c01055
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

5.9

Divison category: 
Polymer Science & Engineering
Database: 
Web of Science (WoS)

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