Helical folding in heterogeneous foldamers without inter-residual backbone hydrogen-bonding

TitleHelical folding in heterogeneous foldamers without inter-residual backbone hydrogen-bonding
Publication TypeJournal Article
Year of Publication2012
AuthorsPriya, G, Kotmale, AS, Gawade, RL, Mishra, D, Pal, S, Puranik, VG, Rajamohanan, PR, Sanjayan, GJ
JournalChemical Communications
Volume48
Issue71
Pagination8922-8924
Date PublishedJUL
ISSN1359-7345
Abstract

This communication describes a set of hybrid foldamers that do not feature inter-residual, but intra-residual backbone hydrogen-bonding, yet adopt a preferentially folded conformation displaying right-handed helical architecture. Conformational ordering is apparently due to the combined conformational restrictions imposed by the conformationally restricted individual amino acid residues with which the oligomers are made of.

DOI10.1039/c2cc33235c
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

6.378

Divison category: 
Center for Material Characterization (CMC)
Central NMR Facility
Organic Chemistry
Physical and Materials Chemistry