H-atom site exchange in an iridium trans-dihydrogen/hydride complex, trans-[Ir(H)(?2-H2)(iPr)4(POCOP)(DMAP)]+
| Title | H-atom site exchange in an iridium trans-dihydrogen/hydride complex, trans-[Ir(H)(?2-H2)(iPr)4(POCOP)(DMAP)]+ |
| Publication Type | Journal Article |
| Year of Publication | 2023 |
| Authors | Agrawal, NK, Gayathridevi, S, Dash, SR, Vanka, K, Jagirdar, BR |
| Journal | Dalton Transactions |
| Volume | 52 |
| Issue | 39 |
| Pagination | 13858-13863 |
| Date Published | OCT |
| Type of Article | Article |
| ISSN | 1477-9226 |
| Abstract | Treatment of trans-[Ir(H)(N)(2)((iPr)4)(POCOP)(DMAP)][BAr4f] (2) with H-2 (1 bar) under ambient conditions (298 K) results in the formation of a trans-[Ir(H)(?(2)-H-2)((iPr)4)(POCOP)(DMAP)][BAr4f] (3) complex. Complex 3 exhibits H-atom site exchange between the bound H-2 and the hydride ligands which are mutually trans to one another. A plausible mechanism of this exchange involves metal-ligand cooperativity as studied by computations. |
| DOI | 10.1039/d3dt02366d |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4 |
Divison category:
Physical and Materials Chemistry
Database:
Web of Science (WoS)
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