Green synthesis of cyclohexanone to adipic acid over Fe-W oxides incorporated mesoporous carbon support
| Title | Green synthesis of cyclohexanone to adipic acid over Fe-W oxides incorporated mesoporous carbon support |
| Publication Type | Journal Article |
| Year of Publication | 2022 |
| Authors | Mekala, SPrasad, Prabu, M, Gawali, SDatta, Gopakumar, K, Gogoi, P, Bhatkar, ARavindra, Mohapatra, G, Unnikrishanan, E, Raja, T |
| Journal | Catalysis Communications |
| Volume | 168 |
| Pagination | 106466 |
| Date Published | AUG |
| Type of Article | Article |
| ISSN | 1566-7367 |
| Keywords | Adipic Acid, Liquid phase oxidation, mesoporous carbon, Redox center |
| Abstract | We have prepared iron and tungsten oxides incorporated mesoporous carbon (MC) catalysts using a simple hydrothermal methodology with different carbon sources, and the catalytic performance was investigated for cyclohexanone oxidation. An adequate amount of metal oxide loading has displayed a key role in the selective catalyst for adipic acid (AA) synthesis. The MC catalyst has shown its prime activity under the influence of redox properties of W5+/W6+ and Fe2+/Fe3+ as promoters. The 10%Fe 90%W-MC fructose as a carbon source catalyst has provided its best selectivity of 87% for AA at 120 ?C. |
| DOI | 10.1016/j.catcom.2022.106466 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.510 |
Divison category:
Catalysis and Inorganic Chemistry
Database:
Web of Science (WoS)