Gold(I)-catalyzed hydroaminaloxylation and petasis-ferrier rearrangement cascade of aminaloalkynes

TitleGold(I)-catalyzed hydroaminaloxylation and petasis-ferrier rearrangement cascade of aminaloalkynes
Publication TypeJournal Article
Year of Publication2016
AuthorsGade, AB, Patil, NT
JournalOrganic Letters
Volume18
Issue8
Pagination1844-1847
Date PublishedAPR
ISSN1523-7060
Abstract

An efficient method has been developed to generate a diverse array of indolizidines and quinolizidines from readily available aminaloalkynes via a gold(I)-catalyzed hydroaminaloxylation and Petasis-Ferrier rearrangement cascade. The method enabled a formal synthesis of (+/-)-antofine.

DOI10.1021/acs.orglett.6b00585
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

6.732

Divison category: 
Organic Chemistry