Gold(I)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes
| Title | Gold(I)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes |
| Publication Type | Journal Article |
| Year of Publication | 2018 |
| Authors | Akram, MO, Shinde, PS, Chintawar, CC, Patil, NT |
| Journal | Organic & Biomolecular Chemistry |
| Volume | 16 |
| Issue | 16 |
| Pagination | 2865-2869 |
| Date Published | APR |
| Type of Article | Article |
| Abstract | Gold(I)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes are described. This redox neutral strategy offers an efficient approach to diverse biaryls, vinyl arenes and arylacetylenes. Monitoring the reaction with NMR and ESI-MS provided strong evidence for the in situ formation of Ph3PAuIR (R = aryl, vinyl and alkynyl) species which is crucial for the activation of aryldiazonium salts. |
| DOI | 10.1039/C8OB00630J |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.564 |
Divison category:
Organic Chemistry
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