Gold(I)-catalysed [1,3] O -> C rearrangement of allenyl ethers
| Title | Gold(I)-catalysed [1,3] O -> C rearrangement of allenyl ethers |
| Publication Type | Journal Article |
| Year of Publication | 2014 |
| Authors | Kona, CNaidu, Ramana, CV |
| Journal | Chemical Communications |
| Volume | 50 |
| Issue | 17 |
| Pagination | 2152-2154 |
| Date Published | JAN |
| ISSN | 1359-7345 |
| Abstract | A simple and rapid access to the alpha-substituted acryl aldehydes has been provided by developing a gold-catalysed [1,3] rearrangement of the allenyl ethers importantly with a record turnover frequency of 4600 h(-1) (at 0.05 mol% of the catalyst concentration) in homogeneous gold(I) catalysis. |
| DOI | 10.1039/c3cc49629e |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 7.00 |
Divison category:
Organic Chemistry