Gold and hypervalent iodine(iii): liaisons over a decade for electrophilic functional group transfer reactions

TitleGold and hypervalent iodine(iii): liaisons over a decade for electrophilic functional group transfer reactions
Publication TypeJournal Article
Year of Publication2020
AuthorsBanerjee, S, Bhoyare, VW, Patil, NT
JournalChemical Communications
Volume56
Issue18
Pagination2677-2690
Date PublishedMAR
Type of ArticleArticle
ISSN1359-7345
Abstract

Over the last two decades, hypervalent iodine(iii) reagents have evolved from being `bonding curiosities' to mainstream reagents in organic synthesis, in particular, electrophilic functional group transfer reactions. In this context, gold catalysts have not only emerged as a unique toolbox to facilitate such reactions (especially alkynylations) but also opened new possibilities with their different modes of reactivities for other functional group transfer reactions (acetoxylations and arylations). This feature article critically summarizes hitherto all such Au-catalyzed electrophilic functional group transfer reactions with hypervalent iodine(iii) reagents, emphasizing their mechanistic aspects.

DOI10.1039/d0cc00106f
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

5.996

Divison category: 
Organic Chemistry

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