Functionalization of single-walled carbon nanotubes with azides derived from amino acids using click chemistry

TitleFunctionalization of single-walled carbon nanotubes with azides derived from amino acids using click chemistry
Publication TypeJournal Article
Year of Publication2008
AuthorsKumar, I, Rana, S, Rode, CV, Cho, JWhan
JournalJournal of Nanoscience and Nanotechnology
Volume8
Issue7
Pagination3351-3356
Date PublishedJUL
Type of ArticleArticle
ISSN1533-4880
KeywordsAmino acids, Carbon nanotubes, Click chemistry, Functionalization
Abstract

Single-walled carbon nanotubes (SWCNTs) were chemically functionalized with amino acid-based moieties. The covalent functionalization of alkyne-derived SWCNTs with well defined azides derived from amino acids was accomplished through Cu(I)-catalyzed Huisgen [3+2] dipolar cycloaddition click chemistry. Transmission electron microscopy, Raman spectroscopy, and infrared spectroscopic measurements confirmed the functionalization of SWCNTs by organic molecules derived from amino acids, and the resulting material showed some good solubility in the organic solvents such as tetrahydrofuran, CH2Cl2, and CHCl3.

DOI10.1166/jnn.2008.109
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

1.338

Divison category: 
Catalysis and Inorganic Chemistry