Flexible dicarboxylate based pillar-layer metal organic frameworks: differences in structure and porosity by tuning the pyridyl based N, N ` linkers
| Title | Flexible dicarboxylate based pillar-layer metal organic frameworks: differences in structure and porosity by tuning the pyridyl based N, N ` linkers |
| Publication Type | Journal Article |
| Year of Publication | 2014 |
| Authors | Dey, R, Bhattacharya, B, Pachfule, P, Banerjee, R, Ghoshal, D |
| Journal | CrystEngComm |
| Volume | 16 |
| Issue | 11 |
| Pagination | 2305-2316 |
| Date Published | DEC |
| Abstract | {Dicarboxylate supported metal organic hybrids of Co(II), Zn(II) and Cd(II) have been synthesized using two different pyridyl based N, N' linkers having Schiff base functionalized site. The use of flexible dicarboxylate glutarate in designing such frameworks has created a marked diversity in topology. The different N, N' donor linkers also played an active part in the channel modification in the synthesized MOFs. The structural and topological diversity has been analyzed from the single crystal X-ray structure. Five compounds, {[Co(azpy)(glut)]center dot(CH3OH)}(n) (1), {[Co(meazpy)(glut)(H2O)(2)]center dot (H2O)(3) |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.849 |
Divison category:
Physical and Materials Chemistry