Few-layer graphene lithiophilic and sodiophilic diffusion layer on porous stainless steel as lithium and sodium metal anodes

TitleFew-layer graphene lithiophilic and sodiophilic diffusion layer on porous stainless steel as lithium and sodium metal anodes
Publication TypeJournal Article
Year of Publication2023
AuthorsPatrike, A, Wasnik, K, Shelke, MV
JournalChemistry-An Asian Journal
Volume18
Issue7
Date PublishedAPR
Type of ArticleArticle
ISSN1861-4728
KeywordsFew layer graphene, Free-standing, Li and Na metal functional host, Na depth profiles, post-cycling XPS
Abstract

In order to subdue the obvious problem of uneven electric field distribution on regularly used copper/aluminum current collectors for alkali metal batteries, graphene on porous stainless steel (pSS_Gr) was fabricated using the ion etching technique that is employed as an effective host for lithium and sodium metal anodes. The binder-free pSS_Gr demonstrated stable Li plating and stripping at areal current and capacity of 6 mA cm(-2) and 2.54 mAh cm(-2), respectively, for over 1000 cycles with 98% coulombic efficiency (C.E.). Also, in the case of Na metal anode, the host has shown stable performance at 4 mA cm(-2) and 1 mAh cm(-2) over 1000 cycles with similar to 100% C.E.. Further, a full cell composed of Li-plated pSS_Gr as an anode and LiFePO4 as a cathode is electrochemically tested at 50 mA g(-1) current density with stable 100 cycles.

DOI10.1002/asia.202300068
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

4.839

Divison category: 
Physical and Materials Chemistry
Database: 
Web of Science (WoS)

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