Feasibility studies and dynamics of catalytic liquid phase esterification reactions in a micro plant
Title | Feasibility studies and dynamics of catalytic liquid phase esterification reactions in a micro plant |
Publication Type | Journal Article |
Year of Publication | 2008 |
Authors | Kulkarni, AA, Zeyer, K-P, Jacobs, T, Kaspereit, M, Kienle, A |
Journal | Chemical Engineering Journal |
Volume | 135 |
Pagination | S270-S275 |
Date Published | JAN |
Type of Article | Article |
ISSN | 1385-8947 |
Keywords | chromatographic reactor, heterogeneous catalysis, integrated process, modular micro reactor |
Abstract | We present a new micro reactor concept which is suitable for investigations of heterogeneously catalyzed liquid phase reactions. In the set-up two reactants are mixed in a commercially available interdigital micro mixer. The outlet of the micro mixer is connected to a modular micro reactor that consists of stacked plates. Each plate contains a milled meandering channel filled with catalyst beads. By using a variable number of plates the residence time can be manipulated and thus adjusted for a specific task. The synthesis of butyl acetate is considered as a model reaction since it has been investigated in detail in conventional reaction systems. In a first step, some experimental results of the heterogeneously catalyzed reaction are presented. In the second part, the set-up is operated as a chromatographic reactor. Dynamic behaviour is investigated applying the frontal analysis mode and the elution chromatography mode. (c) 2007 Elsevier B.V. All rights reserved. |
DOI | 10.1016/j.cej.2007.07.024 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 5.31 |